10.2 Ozone Depletion

The Ozone Layer

Ozone molecule shape and structure
Figure 1. The ozone molecule is comprised of three oxygen atoms covalently bonded. “Ozone” by UCAR (Randy Russell)  is licensed under CC BY-SA.

Ozone (O3) is a gaseous molecule that occurs in different parts of the atmosphere (Figure 1). It is very reactive chemically and is dangerous to plant and animal life when present in the lower portions of the atmosphere. This type of ozone, called ground-level ozone, is a significant hazard to human health and is associated with pollution from vehicle exhaust and other anthropogenic emissions (see section 10.1).

Ozone that occurs in the upper atmosphere is naturally occurring and beneficial to life due to its role in blocking harmful radiation from the sun. This type of ozone is called stratospheric ozone. Ozone in the stratosphere (Figure 2) forms when the two oxygen atoms in an O2 molecule are broken apart by the energy of sunlight. Each lone oxygen atom can then combine with a different O2 molecule to form O3, ozone. The ozone layer is the portion of the stratosphere where ozone molecules are present, mixed in among the other gases that comprise the atmosphere (Figure 2).

Layers of the atmosphere, showing the ozone layer in the stratosphere
Figure 2. The ozone layer occurs in the region of the atmosphere called the stratosphere. This Photo by NC Climate Office is licensed under CC BY-SA.

Radiation from the sun is also called electromagnetic radiation, or simply referred to as light. The sun emits different types of light including but not limited to x-rays, visible light, microwaves, and ultraviolet light. The various types of light are distinguished by their different wavelengths. As wavelength decreases, the amount of energy in that light increases. Ultraviolet light, for example, has shorter wavelengths than visible light and is thus more energetic. Ozone molecules absorb ultraviolet (UV) light, which is advantageous for life on Earth because UV light can break down important biomolecules such as DNA, which can lead to cell death and mutations.

Ozone Depletion

Unfortunately, the ozone layer that protects life on Earth from harmful UV light has been depleted due to human activities. The ozone depletion process begins when CFCs (chlorofluorocarbons) and other ozone-depleting substances (ODS) are emitted into the atmosphere. CFCs were used by industry as refrigerants, degreasing solvents, and propellants. In the lower atmosphere, CFC molecules are extremely stable chemically and do not dissolve in rain, and thus can linger for long periods. After several years, ODS molecules eventually reach the ozone layer in the stratosphere, which starts at about 10 kilometers above the Earth’s surface.

chlorine catalytic cycle that destroys ozone as described in text above
Figure 3. CFCs destroy ozone (O3) when a chlorine atom breaks lose from the CFC and interacts with the oxygen atoms in the ozone molecule. This Photo by UCAR is licensed under CC BY-SA-NC.

Once in the stratosphere, CFCs and other ODS destroy ozone molecules. In the case of CFCs, UV light in the stratosphere knocks loose a chlorine atom from the molecule, which can then destroy numerous ozone molecules, as shown in Figure 3.

In effect, ODS are removing ozone faster than it is created by natural processes (as described above), and this leads to a thinning of the ozone layer. This thinning represents a reduction in concentration of ozone molecules in a particular portion of the stratosphere. Areas where the ozone layer has thinned are commonly referred to as holes, although this is not entirely accurate because ozone is still present, it just exists at concentrations much lower than normal.

Policies to Reduce Ozone Destruction

Tackling the issue of ozone layer destruction is an example of global cooperation that produced meaningful action on a large-scale environmental problem. In 1973, scientists first calculated that CFCs could reach the stratosphere and destroy ozone. Based only on their calculations, the United States and most Scandinavian countries banned CFCs in spray cans in 1978.

But more confirmation that CFCs break down ozone was needed before additional action was taken. In 1985, members of the British Antarctic Survey reported that a 50% reduction in the ozone layer had been found over Antarctica in the previous three springs, a very important finding.

Two years after that seminal British Antarctic Survey report, an agreement titled the “Montreal Protocol on Substances that Deplete the Ozone Layer” was ratified by nations all over the world. The Montreal Protocol, as it is commonly called, controls the production and emission of 96 chemicals that damage the ozone layer. As a result, CFCs have been mostly phased out since 1995, although they were used in developing nations until 2010. Some of the less hazardous substances will not be phased out until 2030. The Montreal Protocol also requires that wealthier nations donate money to develop technologies that will replace these chemicals.

Map of ozone levels over North America
Figure 4. Ozone levels over North America decreased between 1974 and 2009. Models of the future predict what ozone levels would have been if CFCs were not being phased out. Warmer colors indicate more ozone.

The Montreal Protocol was a success and scientists have found that the ozone layer is recovering and the size of the ozone “holes” are shrinking, thanks to a drastic reduction in emission of ODS like CFCs. The recovery process is slow, however, because CFCs take many years to reach the stratosphere and can survive there a long time before they break down and are rendered harmless. Thus, it will take many more decades for the ozone layer to fully recover.

Constant vigilance and monitoring are needed, however, as illegal production and emission of CFCs and other ODS threaten recovery efforts. In 2018, scientists from the US National Oceanic and Atmospheric Administration reported that emissions of a particular type of CFC had increased 25% since 2012. Follow-up studies have since approximated the emissions as originating in particular regions of eastern Asia.

Health and Environmental Effects of Ozone Layer Depletion

The ozone layer absorbs UV-B and UV-C light, protecting life on Earth from its harmful effects
Figure 5. The ozone layer absorbs UV-B and UV-C light, protecting life on Earth from its harmful effects. This Photo by NASA is licensed under CCO Public Domain.

There are three types of UV light, each distinguished by their wavelengths: UV-A, UV-B, and UV-C. Stratospheric ozone molecules absorb all of the sun’s UV-C light and most of its UV-B light (Figure 5).

Reductions in stratospheric ozone levels led to higher levels of UV-B reaching the Earth’s surface, which is a serious hazard to human health. Studies have shown that in the Antarctic the amount of UV-B measured at the surface can double due to thinning of the ozone layer. UV-B is harmful to cells because it can interact with biomolecules like DNA and damage it. This can lead to mutations and cell death. UV-B cannot penetrate multicellular organisms very far and thus tends to only affect cells near the surface, such as in the skin of animals. Microbes like bacteria, however, are composed of only one cell and can therefore be killed by UV-B.

Laboratory and epidemiological studies demonstrate that UV-B causes certain types of skin cancers in humans and plays a major role in development of malignant melanoma (a particularly dangerous form of skin cancer). In addition, UV-B causes cataracts, a clouding of the lens in the eye that can lead to poor vision or even blindness.

It is important to note that all sunlight contains some UV-B light, even with normal stratospheric ozone levels. Therefore, it is important to protect your skin and eyes from the sun. Ozone layer depletion increases the amount of UV-B and the risk of health effects.

Attribution

Essentials of Environmental Science by Kamala Doršner is licensed under CC BY 4.0. Substantially modified from the original by Matthew R. Fisher.

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Environmental Biology by Matthew R. Fisher, Editor is licensed under a Creative Commons Attribution 4.0 International License, except where otherwise noted.

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