, as opposed to , occurs when body temperature increases as thermal energy builds up the body because heat is not transferred out of the body fast enough to keep up with the body’s . We can try to avoid such a situation by minimizing our output to reduce overall (remember, the body has low so doing work means generating ). We can also use our understanding of the , convection, and to ensure maximum transfer away from the body. For example, we can minimize the thickness of clothing to increase conduction, wear light colored clothing to reduce radiation absorbed from the sun, and encourage air circulation (convection).
In some cases our outpaces the rate at which we exhaust heat by conduction, convection and radiation. Our strategy to deal with this situation is sweating. When we sweat some of the water on our skin evaporates into a water vapor. Only the molecules with the most are able to escape the attraction of their fellow water molecules and enter the air. Therefore the evaporating molecules remove more than a fair share of the (thermal energy is just molecular kinetic energy remember). The remaining liquid water molecules then have less thermal energy on average, so they are at a lower and must absorb more energy from your body as they come to with your body again. This process allows the body to dump thermal energy even when the environment is too warm for significant heat loss by conduction, convection, and radiation. The amount of energy removed by evaporation is quantified by the (Lv). For water Lv = 2,260 kJ/kg, which means that for every kilogram of sweat evaporated, 2260 kiloJoules of energy is transferred away from the skin.
A person working in an environment that happens to be very close to body temperature (about 100 °F) would not be able to get rid of thermal energy by conduction, convection, or radiation. If the person was working hard and generating about 250 W of (similar to the thermal power while shivering) then how much sweat would need to be evaporated each hour to keep their body temperature from rising?
In order to keep the body temperature from rising the person needs to get rid of 250 W of thermal energy, that’s 250 J/s. Let’s convert that to per hour:
Each kilogram of water that evaporates removes 2,260,000 J of energy, so only a fraction of a kilogram will need to be evaporated every hour:
The body would need to evaporate 0.4 kg per hour. Water has a of about 1 kg/L, so that would be a of 0.4 L/hr, or roughly 1.7 cups/hr, or 13.5 fluid oz/hr.
The rate at which water will evaporate depends on the liquid and the of the surrounding air. The relative humidity compares how many water molecules are in the vapor phase relative to the maximum number that could possibly be in the vapor phase at the current temperature. A relative humidity of 100% means that no more water molecules can be added to the vapor phase. If the humidity is high, then evaporation will be slow and may not provide sufficient cooling. The takes into account both air temperature and the relative humidity to determine how difficult it will be for your body to . Specifically, the heat index provides the theoretical air temperature that would be required at 20% humidity to create the same difficulty in exhausting heat as the actual temperature and humidity. Heat index values were devised for shady conditions with a light wind. Exposure to full sun or stagnant air can increase feel-like values by up to 15 degrees!
Everyday Examples: Winter Dry Skin
The Pacific Northwest is famous for its winter rain, fog and general high humidity. However, people in the pacific northwest often suffer from dry skin in winter, but not summer when humidity is often less than 20 %. . During winter, humid air is brought in from the outside and warmed by the heating system. That air still contains the same amount of water vapor, but is now at higher temperature, so the relative humidity is significantly reduced, even to the point of causing dry skin.
Boiling and The Bends
We have learned that takes place even when a liquid isn’t boiling, so we may be wondering what causes boiling and how is it different from normal evaporation? Water ordinarily contains significant amounts of dissolved air and other impurities, which are observed as small bubbles of air in a glass of water. The bubbles formed within the water so the inside the bubbles is 100%, meaning the maximum possible number of water molecules are inside the bubble as vapor. Those molecules collide with the walls of the bubble causing an outward pressure. The of the water molecules increases with , so the pressure they exert does as well. At 100 °C the internal pressure exerted by the water vapor is equal to the atmospheric pressure trying to collapse the bubbles, so rather than collapse they will expand and rise, causing boiling. Once water is boiling, any additional input goes into changing liquid water to water vapor, so the water will not increase temperature. Turning up the burner on the stove will not cook the food faster, it will just more quickly boil away (evaporate) the water.
Everyday Examples: The Bends
At high altitude the atmospheric is lower, so molecules of water vapor don’t need to create as much pressure within bubbles to maintain boiling. Therefore, boiling will occur at a lower temperature and cooking foods by boiling will take longer. (Food packaging often gives alternative cook times for high altitude).
The same process is responsible for the bends, which refers to the formation of nitrogen bubbles within the blood upon rapid ascent while diving. You might imaging that you could hang out underwater by breathing through a hose, and that would work in very shallow water. However, the high pressure exerted by water at depths below roughly 2 m (6 ft) would prevent the diaphragm and rib cage from expanding to pull air into the lungs. At greater depths you need to breath from a pressurized container which helps to force air into your lungs against the additional hydrostatic . Of course if you breathed from the container at shallow depth then the pressure would be too high and would cause damage to your lungs. A pressure regulator that outputs the appropriate pressure according to the water depth is the core of the system.
There is always some gas dissolved in your blood, including carbon dioxide, oxygen, and nitrogen. The amount of dissolved gas is determined by the and the . If temperature is high enough, and pressure is low enough, then boiling will occur. Breathing high pressure air from a SCUBA system while at depth forces these gases to dissolve into your blood in the amounts determined by your body temperature and the high .
When ascending, the pressure drops quickly, but the body temperature stays , so the blood gases can begin to boil, starting with Nitrogen. There is not issue with blood here, blood is still at body temperature, but the bubbles are a problem for the . To prevent the bends, you must ascend slowly, allowing the gasses to slowly escape from the blood and be expelled in the breath, without forming large bubbles in the blood.
To treat the bends a patient is placed in a hyperbaric (high pressure) chamber. The high collapses the bubbles and prevents new ones from forming. The pressure is then slowly decreases to allow the blood gasses to escape slowly, simulating a gradual ascent.
We have learned that of liquid molecules removes from the liquid. An exchange of thermal energy will accompany any such . The reverse process of , in which vapor molecules stick together to form a liquid, will bring thermal energy into the liquid. The also quantifies the energy exchanged during condensation.
Changing from solid to liquid, known as , requires energy just as evaporation does. The required to melt a solid will be pulled from the surrounding environment, thus lowering the environment temperature. In similar fashion to vaporization, the amount of energy removed by melting is quantified by a latent heat, in this case the (Lf). For water, Lf = 334 kJ/kg, which means that for every kilogram of ice melted, 334 kiloJoules of energy input is needed. Freezing releases the same amount of energy into the environment that melting requires as input. The temperature at which melting occurs (within a given pressure) is known as the melting point. The melting and boiling points and latent heats of various substances at standard are shown in the following chart:
|Substance||Melting point (ºC)||kJ/kg||kcal/kg||Boiling point (°C)||kJ/kg||kcal/kg|
Everyday Examples: Melting Ice for Drinking Water
Spending more than a day in frozen landscapes (high altitude, high latitude, or both), will require ice/snow to make drinking water. Let’s determine the required to melt 10 kg of ice that started at 0 °C.
First we look up the for water in the previous chart and find Lf = 334 kJ/kg, or 334,000 J/kg. Using this value in the latent heat formula:
Now that we are familiar with the idea of latent heat, let’s combine that with our understanding of the energy required to change temperature, to get a full of the minimum amount of stove fuel required for a three-person, round-trip expedition to the summit of Denali, North America’s highest mountain, at 20,380 ft (6495 m). Allowing for gradual acclimatization to altitude will reduce the likelihood of acquiring high altitude pulmonary edema and/or high altitude cerebral edema, so we will plan 21 days on the mountain.
First, let’s figure out how much water we need. The combination of acclimatization and climbing effort will require at least 4 liters of water per person per day. The total we need is then:
The of water is 1 kg/L so we will also need 252 kg of water. To get that of water we will need to warm and melt that mass of snow each day. The average on the mountain will be -20 °C and we will assume the snow to be melted starts off at this temperature. Let’s find the energy required to warm that mass of -20 °C snow up to 0 °C. We use a chart of specific heats to find cice = 2 kJ/kg = 2,000 J/kg. Using that value in our equation relating heat and temperature change:
Next we need the energy to melt the snow:
So far we need 10,080,000 J + 8,4168,000 J = 94,248,000 J to get ourselves enough water at 0 °C.
Typically the snow is brought to a boil to prevent sickness due to contamination by previous expeditions, and because a hot drink is great for mind and body after hauling a heavy pack and sled through deep snow for 12 hours in sub-zero temperatures at high altitude.
At altitude, the water will boil before reaching 100 °C. According to boiling point vs. altitude graph the boiling point of water at a mountain height of 13,000 ft will be about 190 °F (88 °C) rather than 212 °F (100°C). We will only need to raise the water temperature from 0 °C to 88 °C to achieve boiling. Water has a of 4186 J/(kg C°), so we have:
All told, we need that 92,828,736 J plus our previous 94,248,000 J for a total of 187,076,736 J.
According to data on energy densities in fuel, typical liquid fuels (white gas, gasoline, etc.) will provide roughly 40 MJ (40,000,000 J) of net heating energy per kg of fuel burned. To make our rough estimate the minimum fuel requirement we will assume all of the released by burning the fuel is transferred to the water:
The of liquid fuels is less than water at roughly 0.75 kg/L, so this minimum 4.7 kg of fuel comes out to about 6 liters, or 1.5 gallons. Accounting for heat loss from stove and pot to the environment (especially in windy conditions) the actual requirement could end up substantially greater, depending on conditions. On an actual 3-person, 21-day expedition to the summit of Denali in May of 2012 we used just under 2 gallons of fuel, so our estimate was pretty reasonable.
Check out the following simulations allows you to play with .
- Hyperthermia Patient by Mike Mitchell (photographer) [Public domain], via Wikimedia Commons ↵
- OpenStax University Physics, University Physics Volume 2. OpenStax CNX. Feb 6, 2019 http://firstname.lastname@example.org ↵
- OpenStax, Humidity, Evaporation, and Boiling. OpenStax CNX. Sep 9, 2013 http://cnx.org/contents/030347e9-f128-486f-a779-019ac474ff90@5 ↵
- "Zion National Park Visitor Center" by National Renewable Energy Laboratory, U.S. Department of Energy is in the Public Domain ↵
- "Heat Index" by National Weather Service, NOAA is in the Public Domain ↵
- "Decompression Chamber" by U.S. Navy Mass Communication Specialist 2nd Class Jayme Pastoric, is in the Public Domain. ↵
- [footnote]OpenStax CNX. Feb 27, 2019 http://email@example.com. ↵
The condition of having a body temperature well above the normal range.
The condition of having a body temperature well below the normal range.
rate at which chemical potential energy is converted to thermal energy by the body, batteries, or heat engines. Also, rate at which thermal energy is converted to electrical energy by a thermal power plant.
A quantity representing the effect of applying a force to an object or system while it moves some distance.
ratio of useful work performed to total energy expended
energy stored in the microscopic motion of atoms and molecules (microscopic kinetic energy)
the process by which heat or directly transmitted through a substance when there is a difference of temperature between adjoining regions, without movement of the material
Electromagnetic radiation spontaneously emitted by all objects with temperature above absolute zero.
An amount of thermal energy transferred due to a difference in temperature.
energy which a body possesses by virtue of being in motion, energy stored by an object in motion
a measure of the average kinetic energy of the particles (e.g., atoms and molecules) in an object, which determines how relatively hot or cold an object feels
a two systems are in thermal equilibrium when they do not exchange heat, which means they must be at the same temperature
vaporization that occurs on the surface of a liquid as it changes into the gas phase
Thermal energy input required to change a unit mass of liquid into vapor.
International standard (SI) unit of Energy
relation between the amount of a material and the space it takes up, calculated as mass divided by volume.
a quantity of space, such as the volume within a box or the volume taken up by an object.
a measure of how many water molecules are in the vapor phase relative to the maximum number that could possibly be in the vapor phase at at a given temperature. A relative humidity of 100% means that no more water molecules can be added to the vapor phase.
a measure of how hot feels (according to difficult in exhausting heat) when relative humidity is factored in with the actual air temperature
heat transferred to the environment rather than being used to do useful work
distance traveled per unit time
force per unit area
self-contained underwater breathing apparatus
not changing, having the same value within a specified interval of time, space, or other physical variable
heart, blood and blood vessels
the change of a substance between states of being solid, liquid, or gas (or other more exotic phases)
Process of vapor changing phase into a liquid.
changing phase from solid to liquid.
the thermal energy required to melt a unit mass of a substance
the pressure exerted by the gasses in the atmosphere
a rough value obtained without making a measurement by using prior knowledge and assumptions.
a measurement of the amount of matter in an object made by determining its resistance to changes in motion (inertial mass) or the force of gravity applied to it by another known mass from a known distance (gravitational mass). The gravitational mass and an inertial mass appear equal.
A material property that determines the amount of energy required to raise the temperature one mass unit of the material by one temperature unit.